|
|Section2= |Section3= |Section7= |Section8= }} Dimanganese decacarbonyl is the chemical compound with the formula Mn2(CO)10. This metal carbonyl is an important reagent in the organometallic chemistry of manganese.〔Elschenbroich, C. "Organometallics" (2006) Wiley-VCH: Weinheim. ISBN 978-3-527-29390-2〕 ==Synthesis== The compound was first prepared in low yield by the reduction of manganese iodide with magnesium under CO.〔Brimm, E. O.; Lynch, M. A.; Sesny, W. J. "Preparation and Properties of Manganese Carbonyl" Journal of the American Chemical Society 1954, volume 76, page 3831 - 3835.〕 A more efficient preparation entails reduction of anhydrous MnCl2 with sodium benzophenone ketyl under 200 atmospheres of CO.〔King, R. B. Organometallic Syntheses. Volume 1 Transition-Metal Compounds; Academic Press: New York, 1965. ISBN 0-444-42607-8〕 The availability of inexpensive methylcyclopentadienyl manganese tricarbonyl ("MMT") has led to a low pressure route to Mn2(CO)10.〔King, R. B.; Stokes, J. C.; Korenowski, T. F. "A Convenient Synthesis of Dimanganese Decarbonyl from Inexpensive Starting Materials at Atmospheric Pressure" Journal of Organometallic Chemistry 1968, volume 11, Pages 641-643.〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「dimanganese decacarbonyl」の詳細全文を読む スポンサード リンク
|